Correction: Corrigendum: Stereoinversion of tertiary alcohols to tertiary-alkyl isonitriles and amines
نویسندگان
چکیده
منابع مشابه
Visible-light-mediated, nitrogen-centered radical amination of tertiary alkyl halides under metal-free conditions to form α-tertiary amines.
A mild and operationally convenient amino-functionalization of a range of tertiary alkyl halides by reaction with iminoiodinanes (PhI[double bond, length as m-dash]NNs) and I2 has been developed. According to the mechanistic experiments described within, the reaction is speculated to proceed through a light-promoted, N-centered radical pathway involving a N,N-diiodosulfonamide reactive species....
متن کاملHighly efficient heterogeneous gold-catalyzed direct synthesis of tertiary and secondary amines from alcohols and urea.
Urea, the white gold: The efficient synthesis of tertiary and secondary amines is achieved by heterogeneous gold-catalyzed direct amination of stoichiometric alcohols with urea in good to excellent yields. Via a hydrogen autotransfer pathway, the reactions of primary alcohols with urea give tertiary amines exclusively, while secondary alcohols selectively afford secondary amines.
متن کاملSOA formation from tertiary amines
Secondary organic aerosol formation from reaction of tertiary amines with nitrate radical M. E. Erupe, D. J. Price, P. J. Silva, Q. G. J. Malloy, L. Qi, B. Warren, and D. R. Cocker III Department of Chemistry and Biochemistry, Utah State University, Logan, UT, USA Department of Chemical and Environmental Engineering and College of Engineering, Center for Environmental Research and Technology (C...
متن کاملNi-catalysed, domino synthesis of tertiary alcohols from secondary alcohols.
The use of in situ generated (NHC)-Ni catalytic species (NHC = N-heterocyclic carbene) allows for the synthesis, in short reaction times, of a variety of tertiary alcohols from secondary alcohols through a domino oxidation-addition protocol.
متن کاملIron catalyzed oxidative cyanation of tertiary amines.
Iron(ii) and iron(iii) salts catalyze the oxidative alpha-cyanation of tertiary amines by trimethylsilyl cyanide in the presence of tert-butylhydroperoxide under acid-free conditions at room temperature.
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ژورنال
عنوان ژورنال: Nature
سال: 2013
ISSN: 0028-0836,1476-4687
DOI: 10.1038/nature12795